Beilstein J. Org. Chem.2014,10, 163–193, doi:10.3762/bjoc.10.14
products; total synthesis; vinylcyclopropane–carbaldehyderearrangement; Introduction
The first documented divinylcyclopropane–cycloheptadiene rearrangement dates back to 1960 occuring during studies of Vogel and coworkers [1][2] on the thermal rearrangement of small carbocycles. Although the desired cis
two different modes for the heteroatom incorporation into the DVCPR, as part of the cyclopropane moiety or as part of one of the vinyl moieties. All variants are covered in the following.
The Reisman group [12][212] observed an intermediate vinylcyclopropanecarbaldehyderearrangement on their way
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Graphical Abstract
Scheme 1:
Vogel’s first approach towards the divinylcyclopropane rearrangement [4] and characterization of cis-d...